Electrochemical Investigation of Antibacterial Laser Dye Compound in 1,2-Dichloroethane at a Platinum Electrode

نویسندگان

  • Abdullah Mohamed Asiri Chemistry Department, Faculty of Science, King Abdul Aziz University, P.O. Box 80203, Jeddah 21589, SAUDI ARABIA
  • Elsayed Hassan El-Mossalamy Chemistry Department, Faculty of Science, King Abdul Aziz University, P.O. Box 80203, Jeddah 21589, SAUDI ARABIA
چکیده مقاله:

Diolefinic antibacterial laser dye namely 1,4-Bis[2-(4-Pyridyl) Vinyl] Benzene (4PVB)have been investigated electrochemically using cyclic voltammetry, chronoamperometry, convolution and deconvolution voltammetry combined with digital simulation techniques at a platinum electrode in 0.1 mol / L Tetra Butyl Ammonium Perchlorate (TBAP) in  solvent 1,2-dichloroethane.  The diolefinic species were reduced by consuming  two sequential electrons to form radical anion and dianion. The second electron transfer was followed by chemical step i.e the electrode reaction proceed as EEC scheme. In scanning the potential to positive direction, the diolefinic  laser dye compound was oxidized by loss of one electron, which was followed by a fast chemical  process ( isomerization or association). The pathway of electrode reaction and the electrochemical parameters of the investigated compound were discussed & determined using cyclic voltammetry and chronoamperometry techniques. The extracted electrochemical parameters were verified and confirmed via digital simulation and convolutive voltammetry methods. 

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

electrochemical investigation of antibacterial laser dye compound in 1,2-dichloroethane at a platinum electrode

diolefinic antibacterial laser dye namely 1,4-bis[2-(4-pyridyl) vinyl] benzene (4pvb)have been investigated electrochemically using cyclic voltammetry, chronoamperometry, convolution and deconvolution voltammetry combined with digital simulation techniques at a platinum electrode in 0.1 mol / l tetra butyl ammonium perchlorate (tbap) in  solvent 1,2-dichloroethane.  the diolefinic species were ...

متن کامل

The investigation of pyrocatechol electrochemical mechanism in presence of nitrite ion on platinum electrode

In this study, the electrochemical mechanism of catechol in presence and absence of nitrite ion, is investigated in phosphate buffer medium (pH=7) using platinum electrode through cyclic voltammetry method in various scan rates. Electrochemical oxidation of catechol showed how quinone has changed to o-benzoquinone and also how o-benzoquinone has reacted with nitrite ion and potential scan rate ...

متن کامل

Electrochemical behaviour of iodide at a rotating platinum disk electrode in methanol

The oxidation of iodide at a rotaling platinum disk electrode in methanol has been studied. At low concentrations only one oxidation wave is seen, but at higher concentrations two steps are discerned. This is in accordance with the theory, assuming that the equilibrium between iodide, ttiiodide and iodine is reached fast and the oxidation of iodide to iodine occurs reversibly. only in approxima...

متن کامل

Electrochemical Degradation of Acridine Orange Dye at Ru-Doped Platinum Anode in Aqueous Solution

Degradation of acridine orange (AO) in aqueous solution by anodic oxidation with a Ru-doped Pt electrode (RuDPt) can be applied to the remediation of waste waters containing acridine orange. This environmentally friendly method decontaminates completely aqueous solutions of this dye. The COD value decreases to ~98% of the initial COD. Acridine orange (AO) is more rapidly removed in RuDPt electr...

متن کامل

Enhanced Electrochemical Catalytic Efficiencies of Electrochemically Deposited Platinum Nanocubes as a Counter Electrode for Dye-Sensitized Solar Cells

Platinum nanocubes (PtNCs) were deposited onto a fluorine-doped tin oxide glass by electrochemical deposition (ECD) method and utilized as a counter electrode (CE) for dye-sensitized solar cells (DSSCs). In this study, we controlled the growth of the crystalline plane to synthesize the single-crystal PtNCs at room temperature. The morphologies and crystalline nanostructure of the ECD PtNCs were...

متن کامل

Electrochemical Treatment Of Malachite Green Dye Solution Using Iron Electrode

Present study was performed to investigate the variables that influence the removal efficiency of malachite green (aniline) dye from aqueous solution by an electrochemical (EC) technique. The batch EC studies were performed using iron electrode to evaluate the effect of operating parameters such as pHo and processes parameters such as current density and initial dye concentration. Parameters pH...

متن کامل

منابع من

با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ذخیره در منابع من قبلا به منابع من ذحیره شده

{@ msg_add @}


عنوان ژورنال

دوره 31  شماره 3

صفحات  9- 18

تاریخ انتشار 2012-09-01

با دنبال کردن یک ژورنال هنگامی که شماره جدید این ژورنال منتشر می شود به شما از طریق ایمیل اطلاع داده می شود.

میزبانی شده توسط پلتفرم ابری doprax.com

copyright © 2015-2023